Search results for "Halogen free"

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Electroorganic synthesis of nitriles via a halogen-free domino oxidation–reduction sequence

2015

A direct electroorganic sequence yielding nitriles from oximes in undivided cells is reported. Despite the fact that intermediate nitrile oxides might be formed, the method is viable to prepare benzonitriles without substituents ortho to the aldoxime moiety. This constant current method is easy to perform for a broad scope of substrates and employs common electrodes, such as graphite and lead.

NitrileMetals and AlloysHalogen freeNanotechnologySequence (biology)Oxidation reductionGeneral ChemistryCombinatorial chemistryCatalysisDominoSurfaces Coatings and FilmsElectronic Optical and Magnetic Materialschemistry.chemical_compoundchemistryElectrodeMaterials ChemistryCeramics and CompositesMoietyGraphiteChemical Communications
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ChemInform Abstract: Electroorganic Synthesis of Nitriles via a Halogen-Free Domino Oxidation-Reduction Sequence.

2016

A direct electroorganic sequence yielding nitriles from oximes in undivided cells is reported. Despite the fact that intermediate nitrile oxides might be formed, the method is viable to prepare benzonitriles without substituents ortho to the aldoxime moiety. This constant current method is easy to perform for a broad scope of substrates and employs common electrodes, such as graphite and lead.

chemistry.chemical_compoundNitrilechemistryElectrodeMoietyHalogen freeSequence (biology)Oxidation reductionGeneral MedicineGraphiteCombinatorial chemistryDominoChemInform
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